Organoclay MSDS | SDS

Organoclay MSDS | SDS

Safety Data Sheet

According to Regulation (EU) No.1907/2006, Annex ll ,

According to Regulation (EU) No.1272/2008

Amended by REGULATION (EU) No.453/2010

Alkyl Quaternary Ammonium Bentonite

                                                    SDS Record Number:CSSS-TCO-010-100375

Editing date:27/12/2017                               Version 1.2        Revision date:29/03/2019

1  Identification of the substance and of the company/undertaking

1.1 Product identifier:

Identifacation on the label/Trade name:        Alkyl Quaternary Ammonium Bentonite

Additional identification:                   Organophilic Clay CP-1,CP-2

Identification of the product                 CAS #68953-58-2; EC#273-219-4

Index Number:                            Not available

REACH registration No.:                    Not available

• Relevant identified uses of the substance and uses advised against:

1.2.1 Identified uses of Organoclay MSDS | SDS :

Used as Rheological additive.

     1.2.2 Uses advised against:

        Not available.

• Details of the supplier of the safety data sheet:

Supplier (Only representative):   Chemical Inspection &Regulation Service Limited

Supplier(Manufacturer):         ZheJiang Camp-Shinning New Material Co. Ltd

Address:           Boutique Building, No.1 Jingzhou Road, Hangzhou, China, 310013

Contact person(E-mail):         Not available

Telephone:                   +86-571-86759271

Fax:                        +86-571-23659717

• Emergency telephone Number:

+353 41 980 6916

Available outside office hours?             YES                 NO    X

2  Hazards Identification

2.1 Classification of the substance of Organoclay MSDS | SDS

2.1.1 Classification:

The substance is classified as following according to 67/548/EEC and REGULATION (EC)No1272/2008:

For full text of H-phrases: see section 2.2.

For full text of R-phrases: see section 16.

2.1.2 The most important adverse effects

2.1.2.1 The most important adverse physicochemical effects:

Not applicable.

2.1.2.2 The most important adverse human health effects:

Not applicable.

2.1.2.3 The most important adverse environmental effects:

Chemical Inspection & Regulation Service Limited                       1

Safety Data Sheet

According to Regulation (EU) No.1907/2006, Annex ll ,

According to Regulation (EU) No.1272/2008

Amended by REGULATION (EU) No.453/2010

Alkyl Quaternary Ammonium Bentonite

                                                    SDS Record Number:CSSS-TCO-010-100375

Editing date:27/12/2017                               Version 1.2        Revision date:29/03/2019

Not applicable.

2.2 Label elements:

Hazard Pictograms:                No hazard pictogram is used.

Signal Word(S):                   No signal word is used.

Hazard Statement:                 Not applicable.

Precautionary Statement:            Not applicable

2.3 Other hazards

Not available (PBT, vPvB, Substance is an endocrine disruptor etc.)

3  Composition/information on ingredients

    Substance/Mixture:      Substance

Ingredient(s):

4  First aid measures

 4.1 Description of first aid measures:

    In all cases of doubt, or when symptoms persist, seek medical attention.

 4.1.1 In case of inhalation of Organoclay MSDS | SDS :

      Remove person to fresh air, if breathing is difficult, provide Oxygen and seek medical attention.

 4.1.2 In case of skin contact:

Wash with soap and water.

4.1.3 In case of eyes contact:

      Rinse immediately with water for at least 15 minutes.

4.1.4 In case of ingestion:

Provide symptomatic treatment and seek medical attention.

4.2 Most important symptoms and effects, both acute and delayed

   The product is not classified as harmful to human health effect.

4.3 Indication of any immediate medical attention and special treatment needed

   If skin irritation or rash occurs, get medical advice/attention.

5  Fire-Fighting measures

 5.1 Extinguishing media:

    Suitable extinguishing media: Water fog, foam, dry chemical, or carbon dioxide.

    Unsuitable extinguishing media: Not available.

5.2 Special hazards arising from the substance or mixture

Precautions for flammable organic dusts should be provided. Avoid high dust concentrations, Assure all equipment is properly to prevent static discharges, and vented to provide for potential energy release.

Chemical Inspection & Regulation Service Limited                         2

Safety Data Sheet

According to Regulation (EU) No.1907/2006, Annex ll ,

According to Regulation (EU) No.1272/2008

Amended by REGULATION (EU) No.453/2010

Alkyl Quaternary Ammonium Bentonite

                                                    SDS Record Number:CSSS-TCO-010-100375

Editing date:27/12/2017                               Version 1.2        Revision date:29/03/2019

5.3 Advice for fire-fighters:

  As in any fire, wear a self—contained breathing apparatus in pressure-demand, MSHA/NIOSH(approved or equivalent),and full protective gear.

6  Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures:

6.1.1 For non-emergency personnel:

      Remove ignition sources. Provide adequate ventilation. Avoid inhalation of vapour or dust. Avoid skin and eye contact. Wear an air-purifying dust respirator and chemical gloves. Wear eye protection to prevent dust from entering the eyes.

6.1.2 For emergency responders:

Wear an air-purifying dust respirator and chemical gloves. Wear eye protection to prevent dust from entering the eyes. Use proper personal protective equipment as indicated in Section 8.

6.2 Environmental Precautions:

Avoid disposing into drainage/sewer system or directly into the aquatic environment. Keeping away from drains, surface-and ground-water and soil.

6.3 Methods for Containment and Cleaning up:

Minimize dusting. Caution: May cause a slippery condition when wet. Sweep/shovel material Into a drum for re-use or disposal.

6.4 Reference to other sections:

See Section 7 for information on safe handling.

See Section 8 for information on personal protection equipment

See Section 13 for information on disposal

6.5 Additional information:

Wet clean or vacuum up solids.

Don’t use a brush or compressed air for cleaning surfaces or clothing.

Clear spills immediately.

7  Handling and storage

7.1 Precautions for safe handling:

7.1.1 Protective measures:

Precaution for flammable organic dusts should be provide. Avoid high dust concentrations. Assure all equipment is properly grounded to prevent static discharges, and vented to provide for potential energy release. Control high dust concentrations while handling through the use of Ventilation or other suitable controls.

7.1.2 Advice on general occupational hygiene:

Do not eat, drink and smoke in work areas. Wash hands after use. Remove contaminated clothing and protective equipment before entering eating areas.

7.2 Conditions for safe storage, including any incompatibilities:

Keep container tightly closed. Keep container in a cool, well-ventilated area.

7.3 Specific end use(s):

     Not applicable.

8 Exposure control/personal protection

8.1 Control parameters:

Chemical Inspection & Regulation Service Limited                     3

Safety Data Sheet

According to Regulation (EU) No.1907/2006, Annex ll ,

According to Regulation (EU) No.1272/2008

Amended by REGULATION (EU) No.453/2010

Alkyl Quaternary Ammonium Bentonite

                                                    SDS Record Number:CSSS-TCO-010-100375

Editing date:27/12/2017                               Version 1.2        Revision date:29/03/2019

8.1.1 Occupational exposure limits: ACGIH-TLV 8hr; TWA:10mg/m3, inhalable fraction; OSHA-PEL 8hr. TWA Dusts: 10mg/m3 classified.

8.1.2 Additional exposure limits under the conditions of use: Not available.

8.1.3 DNE/DMEL and PNEC-Values: Not available.

8.2 Exposure controls

8.2.1 Appropriate engineering controls:

Use local exhaust ventilation if airborne concentrations are above recommended exposure limits.

8.2.2 Individual protection measures, such as personal protective equipment:

Eye/face protection:       Use safety glasses/gloves.

Hand protection:          Use chemical resistant goggles.

Body protection:          Protective garments not normally required.

Respiratory protection:     Use an air-purifying dust respirator if airborne concentration levels are above exposure limits

Thermal hazards:         Wear suitable protective clothing to prevent heat.

8.2.3 Environmental exposure controls:

Avoid discharge into the environment. This material and its container must be disposed of as hazardous waste.

According to local regulations. Federal and official regulations.

9  Physical and chemical properties

9.1 Information on basic physical and chemical properties

Appearance:                                              Fine white Powder

Colour:                                                  White

Odour：                                                 Odourless

Odour threshold                                           Not available.

pH:                                                     3-7

Melting point/range(℃)：                                   Not available

Boiling point/range(℃)：                                   Not available

Flash point(℃):                                           Not available

Evaporation rate:                                           Not applicable

Flammability (solid ,gas):                                    Not applicable

Ignition temperature(℃):                                    Not available

Upper/lower flammability/explosive limits:                      Not available

Vapour pressure(25℃)：                                    Not available

Vapour density:                                            Not available

Relative Density(20℃)：                                    1.65-1.75

Bulk density(kg/m³)：                                       Not available

Water solubility(g/l) at 20℃：                                Insoluble in water

n-Octanol/Water(log Po/w):                                  Not determined

Auto-ignition temperature:                                   Not available

Decomposition temperature：                                Not available

Viscosity, dynamic(Pa S):                                    2000-4000

Explosive properties：                                      Not applicable

Oxidising properties:                                       Not applicable

Loss on ignition (dry sample,1000℃)                          ≤32%

9.2 Other information:

Fat solubility(solvent-oil to be specified) etc:      Not available

Surface tension:                             Not available

Dissociation constant in water(pKa):             Not available

Chemical Inspection & Regulation Service Limited                     4

Safety Data Sheet

According to Regulation (EU) No.1907/2006, Annex ll ,

According to Regulation (EU) No.1272/2008

Amended by REGULATION (EU) No.453/2010

Alkyl Quaternary Ammonium Bentonite

                                                    SDS Record Number:CSSS-TCO-010-100375

Editing date:27/12/2017                               Version 1.2        Revision date:29/03/2019

Oxidation-reduction Potential:                Not available

Loss on ignition (dry sample,1000℃)          33-36%

10  Stability and reactivity

    10.1 Reactivity

        The substance is stable under normal storage and handling conditions.

    10.2 Chemical stability:

        Stable under normal temperatures and pressures.

10.3 Possibility of hazardous reactions:

Under normal conditions, not hazardous reactions will occur.

10.4 Conditions to avoid:

 Incompatible materials, moisture.

10.5  Incompatible materials:

 Strong oxidizing agents. Strong acids.

10.6 Hazardous decomposition products:

In case of fire, possible emission of carbon monoxide, carbon dioxide, organic chlorides and ammonica.

11  Toxicological information

11.1 Toxicokinetics, metabolism and distribution

 Non-human toxicological data:         Not available

Method:                            Not available

Dosis:                              Not available

Routes of administration:             Not available

Results:                            Not available

Absorption:                         Not available

Distribution:                        Not available

Metabolism:                        Not available

Excretion:                          Not available

11.2 Information on toxicological effects

Acute toxicity:

LD50 (Oral, Rat):                      20,000mg/kg

LD50 (Dermal Rabbit):                  Not available

LD50 (Inhalation, Rat):                  Not available

Skin corrosion/Irritation:                No irritating.

Serious eye damage/irritation:            No irritating.

Respiratory or skin sensitization:         Not classified

Germ cell mutagenicity:                 Not classified

Carcinogenicity:                       Not classified

Chemical Inspection & Regulation Service Limited                          5

Safety Data Sheet

According to Regulation (EU) No.1907/2006, Annex ll ,

According to Regulation (EU) No.1272/2008

Amended by REGULATION (EU) No.453/2010

Alkyl Quaternary Ammonium Bentonite

                                                    SDS Record Number:CSSS-TCO-010-100375

Editing date:27/12/2017                               Version 1.2        Revision date:29/03/2019

Reproductive toxicity:                 Not classified

STOT-single exposure:                  Not classified

STOT-repeated exposure:              Not classified

Aspiration hazard:                    Not classified

12  Ecological information

Toxicity:

Persistence and degradability:         Biodegradability: Insignificant Degradability

Bioaccumulative potential:            No data available.

Mobility in soil:                     Not available.

Results of PBT & vPvB assessment:     Not applicable.

Other adverse effects:                Not applicable.

13   Disposal considerations

    13.1 Waste treatment methods

         Dispose of in accordance with local regulations, Use licensed waste Handler.

13.2 Prouduct / Packaging disposal:

Dispose of in accordance with local regulations, Use licensed waste Handler.

14  Transport information

15  Regulation information of Organoclay MSDS | SDS

   15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

Relevant information regarding authorization:        Not applicable.

Relevant information regarding restriction:           Not applicable.

Chemical Inspection & Regulation Service Limited                      6

Safety Data Sheet

According to Regulation (EU) No.1907/2006, Annex ll ,

According to Regulation (EU) No.1272/2008

Amended by REGULATION (EU) No.453/2010

Alkyl Quaternary Ammonium Bentonite

                                                    SDS Record Number:CSSS-TCO-010-100375

Editing date:27/12/2017                               Version 1.2        Revision date:29/03/2019

Other EU regulations:                  Employment restrictions concerning young person must be observed. For use only by technically qualified individuals.

Other National regulations:               Not applicable

Chemical Safety Assessment has been carried out?    YES               NO  X

16  Other information of Organoclay MSDS | SDS

16.1 Indication of changes          Version 1.1  Amended by EU No 453/2010

16.2 Relevant R-phrases(number and full text):

Not applicable.

16.3Tranining instructions:

Not applicable.

16.4 Further information:

This information is based upon the present state of our knowledge. This SDS has been compiled and is solely intended for this product.

16.5 Notice to reader:

Employers should use this information only as a supplement to other information gathered by them, and should make independent judgment of suitability of this information to ensure proper use and protect he health and safety of employees.

This information is furnished without warranty, and any use of the product not in conformance with this Safety Data Sheet, or in combination with any other product or process, is the responsibility of the user.

Organoclay MSDS | SDS